1.  In order to receive charitable contribution deduction, you must itemize your deductions using Schedule A.
2.  Make sure the organization is a bonafide qualified organization.
3.  Keep good records, receipts and documentations.  
4.  Contributions of $250 or more must have a written acknowldgement from the organization.
5.  If you contributed a non-cash item with a fair value of $500 or more, you must complete Form 8283 and attach with your return.
source:  http://www.irs.gov/newsroom/article/0,,id=172936,00.html
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